Explanation:
The genotypes PP and Pp determine purple flowers while pp determines white flowers.
A purple-flowered P_ (PP or Pp) plant is self-fertilized and it produces the progeny:
The only way to obtain plants with white flower in the progeny is if both parental plants have a recessive p allele, so the genotype of the original purple-flowered plant is Pp.
The original cross then was Pp x Pp. The expected offspring (from Punnett Square) is 1/4 PP, 1/2 Pp and 1/4 pp. If we only consider the purple-flowered offspring, the proportion of genotypes is 1/3 PP and 2/3 Pp. To breed true, the individuals must produce only homozygous progeny. Only the PP individuals will breed true, so the probability is 1/3.