Respuesta :
Answer:
Δ[tex]_rG=-2753kJ[/tex]
Explanation:
Hello,
Butane's combustion is:
[tex]C_4H_{10}+\frac{13}{2} O_2-->4CO_2+5H_2O[/tex]
Now the change in the Gibbs free energy for this reaction is computed via (don't forget that oxygen's Gibbs free energy of formation is 0 since it is an element):
Δ[tex]_rG=[/tex]4Δ[tex]_fG_{CO_2}+[/tex]5Δ[tex]_fG_{H_2O}[/tex]-Δ[tex]_fG_{C_4H_{10}}[/tex]
Δ[tex]_rG=4(-395kJ/mol)+5(-238kJ/mol)-(-17kJ/mol)[/tex]
Δ[tex]_rG=-2753kJ/mol[/tex]
Now, since the calculation is done for 1 mol of butane, the change in the Gibbs free energy for this fuel is:
Δ[tex]_rG=-2753kJ[/tex]
Best regards.
The change in free energy of the reaction is -5506 KJ/mol
Given the equation of the reaction;
2C4H10(g) + 13O2(g) -------> 8CO2(g) + 10H2O(l)
We have the following information from the question;
ΔGf C4H10(g)= -17kJ/mol
ΔGf O2(g) = 0 KJ/mol
ΔGfCO2(g) = -395 KJ/mol
ΔGf H2O(l) = -238 KJ/mol
Now, we can obtain the ΔGrxn as follows;
[8(-395 KJ/mol) + 10(-238 KJ/mol)] - [2( -17kJ/mol) + 13 (0 KJ/mol)]
ΔGrxn =[(-3160) + (-2380)] - [(-34) + 0]
ΔGrxn = (-5540) + 34
ΔGrxn = -5506 KJ/mol
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