A 23.9 g sample of iridium is heated to 89.7 oC, and then dropped into 20.0 g of water in a coffee-cup calorimeter. The temperature of the water went from 20.1 oC to 22.6 oC. Calculate the specific heat of iridium. (specific heat of water = 4.18 J/g oC).

Respuesta :

Answer:

The specific heat capacity of iridium = 0.130 J/g°C

Explanation:

Assuming no heat losses to the environment and to the calorimeter,

Heat lost by the iridium sample = Heat gained by water

Heat lost by the iridium sample = mC ΔT

m = mass of iridium = 23.9 g

C = specific heat capacity of the iridium = ?

ΔT = change in temperature of the iridium = 89.7 - 22.6 = 67.1°C

Heat lost by the iridium sample = (23.9)(C)(67.1) = (1603.69 C) J

Heat gained by water = mC ΔT

m = mass of water = 20.0 g

C = 4.18 J/g°C

ΔT = 22.6 - 20.1 = 2.5°C

Heat gained by water = 20 × 4.18 × 2.5 = 209 J

Heat lost by the iridium sample = Heat gained by water

1603.69C = 209

C = (209/1603.69) = 0.130 J/g°C

Answer:

0.13J/g°C

Explanation:

The mixture of the Iridium in water is in a thermo-equilibrium since no heat is lost to the environment. i.e The heat lost (-[tex]H_{I}[/tex]) by Iridium is equal to the heat gained ([tex]H_{W}[/tex]) by water. This can be represented as follows;

- [tex]H_{I}[/tex] = [tex]H_{W}[/tex]                          --------------------------(i)

The negative sign shows that heat is lost to the environment...

But;

[tex]H_{I}[/tex] = [tex]m_{I}[/tex] [tex]C_{I}[/tex] Δ[tex]T_{I}[/tex]                --------------------------(ii)

Where;

[tex]m_{I}[/tex] = mass of Iridium

[tex]C_{I}[/tex] = specific heat capacity of Iridium

Δ[tex]T_{I}[/tex] = change in temperature of Iridium = [tex]T_{I2}[/tex] - [tex]T_{I1}[/tex]

[tex]T_{I2}[/tex] = final temperature of Iridium

[tex]T_{I1}[/tex] = initial temperature of Iridium

Also;

[tex]H_{W}[/tex] = [tex]m_{W}[/tex] [tex]C_{W}[/tex] Δ[tex]T_{W}[/tex]            ------------------------(iii)

Where;

[tex]m_{W}[/tex] = mass of water

[tex]C_{W}[/tex] = specific heat capacity of water

Δ[tex]T_{W}[/tex] = change in temperature of water = [tex]T_{W2}[/tex] - [tex]T_{W1}[/tex]

[tex]T_{W2}[/tex] = final temperature of water

[tex]T_{W1}[/tex] = initial temperature of water

From the question;

[tex]m_{I}[/tex] = 23.9g

[tex]C_{I}[/tex] = ?

[tex]T_{I2}[/tex] = 22.6°C      [the same as the final temperature of water]

[tex]T_{I1}[/tex] = 89.7°C

Δ[tex]T_{I}[/tex] = 22.6°C - 89.7°C = -67.1°C

[tex]m_{W}[/tex] = 20.0g

[tex]C_{W}[/tex] = 4.18 J/g °C

[tex]T_{W2}[/tex] = 22.6°C    

[tex]T_{W1}[/tex] = 20.1°C

Δ[tex]T_{W}[/tex] = 22.6°C - 20.1°C = 2.5°C

Substitute the values of [tex]H_{W}[/tex] and [tex]H_{W}[/tex] into equation (i)

- [tex]m_{I}[/tex] [tex]C_{I}[/tex] Δ[tex]T_{I}[/tex] = [tex]m_{W}[/tex] [tex]C_{W}[/tex] Δ[tex]T_{W}[/tex]   -------------------------------(iv)

Now substitute the values of all the variables in equation(iv) into the same;

- 23.9 x [tex]C_{I}[/tex] x - 67.1 = 20.0 x 4.18 x 2.5

1603.69[tex]C_{I}[/tex] = 209

Then, solve for [tex]C_{I}[/tex];

[tex]C_{I}[/tex] = [tex]\frac{209}{1603.69}[/tex]

[tex]C_{I}[/tex] = 0.13

Therefore, the specific heat of Iridium is 0.13J/g°C