Problem 1) From the given options the one that is proper of a chemist is the option B. testing a sample of water form a well. This activity belongs to the field called analytical chemistry which uses special techniques (instruments and processes) to study (separate, identify and quantify matter).
Problem 2) The only of the given procedures that involves a physical change in one substance is the option D. grinding chalk into a fine powder. In this process the molecules remain being the same (same atoms bonded in the number and way).