Respuesta :
Answer: A
Explanation:
q=heat absorbed=+250J
W=−PΔV=−0.5atm×(10−1)
=−4.5L−atm
=−4.5×101J=−454.5J
Now q=ΔE−W
ΔE=q+W=250−454.5
=−204.5J
The change in internal energy (ΔU) is -211 J.
According to the first law of thermodynamics;
ΔU = q + w
ΔU = change in internal energy
q = heat absorbed/ emitted
w = work done on or by the system
We can see from the question that 250 J of heat was absorbed from the surroundings hence q = 250 J
w= PΔV = 0.50 atm(10.1 L - 1.0 L) = 4.55 atm L
But;
1 L atm = 101.325 J
4.55 atm L = 4.55 atm L × 101.325 J/ 1 L atm
= 461 J
Now;
ΔU = 250 J - 461 J
ΔU = -211 J
Note that work done is negative because the gas expands and does work on the surrounding.
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