45 rpm is greater/faster. Convert both measurements to the same unit rate:
45 rpm = (45 rev) / (1 min) = (45 rev) / (60 s) = 0.75 rps
4.71 rad/s = (4.71 rad) / (1 s) • (1 rev) / (2π rad) = (4.71 rev) / (2π s) ≈ 0.74962 rps