No two electrons in an atom or molecule may have the same four electronic quantum numbers, according to the Pauli Exclusion Principle. Only two electrons can fit into an orbital at a time, hence they must have opposing spins.
According to Pauli's exclusion principle, two electrons cannot share the same orbital and must have anti-parallel or opposite spins. Example: Two bonded electrons in a neutral helium atom achieve the opposite spin to occupy the lowest-energy () states.
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